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The lithium secondary batteries with high power density need the electrode materials with both high specific capacity and high tap density. An “outer gel” method by TiCl4 as the raw material has been developed to prepare spherical precursor. High tap density spherical Li4Ti5O12 is synthesized by sintering the mixture of precursor and Li2CO3. La-doped Li4Ti5O12 is also prepared by this method. X-ray...
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