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In the Hf–Cu–Ni–Al quaternary system, the Hf 51 Cu 27.75 Ni 9.25 Al 12 bulk metallic glass (BMG) exhibits the best combination of the large glass-forming ability (GFA) and compressive plasticity. Minor substitution of Nb for Hf in Hf–Cu–Ni–Al BMGs degrades not only the GFA but also plasticity, while the substitution of Ta does not have an appreciable effect on both...
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