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The complex [Ru(bpy)2L]2+, where bpy=2,2′‐bipyridine, L=4‐(phenylethynyl)‐2,2′‐bipyridine, was prepared in its racemic and resolved forms (Δ and Λ). The phenylethynyl unit on the bipyridine for the complex acts as a binding site for α‐cyclodextrin in water (1:1 complex, K=3390 L mol−1) or β‐cyclodextrin (2:1 complex, K1=887 L mol−1, K2=8070 L mol−1). The presence of the cyclodextrin provides partial...
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