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Hydrothermal synthesis has afforded a pair of paramagnetic divalent metal diphenate coordination polymers containing long-spanning bis(4-pyridylformyl)piperazine (4-bpfp) ligands. Single-crystal X-ray diffraction revealed an important structure directing role on the part of the metal coordination environment. [Cu(diphenate)(4-bpfp)]n (1, diphenate=biphenyl-2,2′-dicarboxylate) shows a system of 2-fold...
Annealing Cu(111) covered with more than 10 ML Co film results in substrate Cu atoms diffusing through the Co film, and forming a Cu overlayer capping the Co film. Through AES and LEED experiments and QKLEED calculation, we found that the coverage of the Cu cap has an important effect on the top layers of the Co film. When the coverage of the Cu cap is less than 0.7 ML, the stacking sequence of the...
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