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This paper is focused on establishing the grafting products of diethylmaleate onto ethylene–α-olefin copolymers of varying comonomer contents. Several commercial ethylene/α-olefin copolymers ranging in comonomer contents from 0.35 to 3.70mol% were used, as well as a hydrogenated polybutadiene (HPB) with a 1,2 unit content of 13.9mol%. The polymers were functionalized with DEM in solution. The experimental...
The relaxation behavior of high density polyethylene functionalized with diethylmaleate has been determined by dynamic mechanical method and thermally stimulated depolarization technique. The transitions observed have been related to the structural parameters as well as the α-olefin comonomer content and degree of grafting, and compared with previous TSDC results on LLPE functionalized with the same...
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