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A novel class of organic phosphates were synthesized and applied in iron catalyst as additive for 1,2-syndiotactic polymerization of 1,3-butadiene in combination with aluminum alkyls (Ali−Bu3 or AlEt3) in hexane at industrial favorable 50–100 °C. Remarkable enhanced polymer productivity (up to 486 kg (polymer)/mol(Fe) h) and excellent 1,2-syndiotactic regularity have been achieved at 50–100 °C in...
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