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Additives that can be oxidized preferentially to the baseline electrolyte are possible of forming a protective cathode interphase, but less attention has been paid to the effect of the additive concentration. Herein, this issue is addressed by evaluating the effect of an easily oxidizable electrolyte additive, tripropyl borate (TPB), on the cyclic stability of high-voltage cathode, LiNi0.5Mn1.5O4...
A simple boron-containing molecule, tripropyl borate (TPB), is used as an electrolyte additive to stabilize the interface between spinel lithium manganese oxide (LiMn2O4) and carbonate-based electrolyte under elevated temperature. Electrochemical measurements indicate that the cyclic stability of LiMn2O4 electrode can be significantly improved by TPB. The capacity retention of LiMn2O4 at 1C after...
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