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Formation of a single‐component charge‐transfer complex (SCCTC) is unveiled in solid state of an intermolecular charge‐transfer molecule 2‐(4‐(1‐phenyl‐1H‐phenanthro[9,10‐d]imidazol‐2‐yl)phenyl)anthracene‐9,10‐dione (PIPAQ). Intermolecular donor–acceptor interactions between two PIPAQ molecules is the primary driving force for self‐association and contributes to intermolecular charge transfer. The...
In article number 1903112, Liang‐Sheng Liao, Chun‐Sing Lee, and co‐workers report the formation of dimeric single‐component charge‐transfer complexes (SCCTCs) by self‐complexation of a donor‐π‐acceptor molecule (PIPAQ), wherein the strong intermolecular charge transfer leads to unusual deep‐red/near‐infrared thermally activated delayed fluorescence. Notably, PIPAQ can be applied in light‐emitting...
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