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Domino reaction of benzo[d]thiazole‐2‐methylamine (S1) has been developed in the presence of MnCl2 ⋅ 4H2O, leading to tetrasubstituted pyrrole coordinated dinuclear Mn(II) complex 1 ([MnClP]2, P−=2,3,4,5‐tetrakis(benzo[d]thiazol‐2‐yl)pyrrol‐1‐ide). The reaction process has been studied by assigning a series of intermediates based on time‐dependent mass spectrometry, control experiments, crystallography,...
Hierarchical zeolites can offer substantial benefits over bulk zeolites in catalysis. A drawback towards practical implementation is their lengthy synthesis, often requiring complex organic templates. This work describes an accelerated synthesis of nanolayered MWW zeolite based on the combination of interzeolite transformation (IZT) with a dual‐templating strategy. FAU zeolite, hexamethyleneimine...