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A new chemiluminescence (CL) system based on the reaction of Ag(III) complex with luminol is, for the first time, reported in this work. Incorporated with a flow injection analyses (FIA), the new CL system has been applied for the determination of free cortisol in human sera. The system is based on the CL reaction of luminol with Ag(III) in alkaline solutions, while cortisol can dramatically enhance...
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