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The structure–activity relationship is a cornerstone topic in catalysis, which lays the foundation for the design and functionalization of catalytic materials. Of particular interest is the catalysis of the hydrogen evolution reaction (HER) by palladium (Pd), which is envisioned to play a major role in realizing a hydrogen‐based economy. Interestingly, experimentalists observed excess heat generation...
Proton Electroreduction
In article number 2202410, Elena L. Gubanova, Aliaksandr S. Bandarenka, Matthias Vandichel, and co‐workers report the structure–activity relations that govern the complex electrochemical processes for the proton electro‐reduction on Pd(hkl) electrodes using a combination of theoretical and experimental approaches. The formation of subsurface hydride results in morphological...
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