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Eggshell membranes were used as biotemplate to fabricate a 3D hierarchical porous Co3O4/ZnO p-n junction film. Multiple catalysis and accelerated electron transfer were achieved on the Co3O4/ZnO-GOx electrode by introducing the p-n junction interface into enzyme loading matrix. A stable and well-defined oxidation peak of glucose was obtained with a largely decreased detection potential of 0.25V. Furthermore,...
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