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Wegweisendes Ligandendesign für die Alkoxycarbonylierung von Alkenen: M. Beller und Mitarbeiter beschreiben in ihrer Zuschrift auf S. 5351 ff. eine neue Klasse von Ferrocenyl‐Liganden für verbesserte Alkencarbonylierungen. Diese Phosphanliganden mit sterisch gehinderten und amphoteren Gruppen an den P‐Atomen nehmen aktiv an der Katalyse teil. Sie lassen sich leicht synthetisieren und zeigen eine höhere...
The development of ligands plays a key role and provides important innovations in homogeneous catalysis. In this context, we report a novel class of ferrocenyl phosphines for the alkoxycarbonylation of industrially important alkenes. A basic feature of our ligands is the combination of sterically hindered and amphoteric moieties on the P atoms, which leads to improved activity and productivity for...
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