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Thin films obtained upon plasma polymerization of D4 and HMDSO precursors at atmospheric pressure are submitted to controlled ethanolysis to produce oligomers amenable to electrospray mass spectrometry. When using high resolution mass spectrometry to assess their elemental composition and tandem mass spectrometry to characterize their end‐groups, a whole set of ethanolysis products is identified,...
This paper aims at describing the synthesis of plasma polymer films by means of atmospheric filamentary plasma dielectric barrier discharge. This work highlights the fact that molecular structures of siloxane based plasma films can be tuned according to the so‐called Yasuda's parameter, which corresponds to the W/F ratios (W = power discharge; F = Monomer flow rate). Indeed, we showed that the plasma...
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