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The hydrosilylation reaction between methyldimethoxysilane and methylvinyldimethoxysilane, catalyzed by the cationic species chloropenta(acetonitrile)ruthenium(II) + (C1), was investigated with density functional theory (DFT). The Chalk–Harrod, Glaser–Tilley and σ-bond metathesis mechanisms were considered as mechanistic possibilities for the reaction and enthalpy profiles of each pathway...
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