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Sulfur poisoning and regeneration are global challenges for metal catalysts even at the ppm level. The sulfur poisoning of single‐metal‐site catalysts and their regeneration is worthy of further study. Herein, sulfur poisoning and self‐recovery are first presented on an industrialized single‐Rh‐site catalyst (Rh1/POPs). A decreased turnover frequency of Rh1/POPs from 4317 h−1 to 318 h−1 was observed...
Sulfur poisoning and regeneration are global challenges for metal catalysts even at the ppm level. The sulfur poisoning of single‐metal‐site catalysts and their regeneration is worthy of further study. Herein, sulfur poisoning and self‐recovery are first presented on an industrialized single‐Rh‐site catalyst (Rh1/POPs). A decreased turnover frequency of Rh1/POPs from 4317 h−1 to 318 h−1 was observed...