The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Transition metal catalyzed C−H phosphorylation remains an unsolved challenge. Reported methods are generally limited in scope and require stoichiometric silver salts as oxidants. Reported here is an electrochemically driven RhIII‐catalyzed aryl C−H phosphorylation reaction that proceeds through H2 evolution, obviating the need for stoichiometric metal oxidants. The method is compatible with a variety...
Eine elektrochemische CAryl‐H‐Phosphorylierung unter Rhodium(III)‐Katalyse läuft unter H2‐Entwicklung ab und benötigt keine zusätzlichen chemischen Oxidationsmittel, wie T.‐B. Wen, H.‐J. Zhang, H.‐C. Xu et al. in ihrer Zuschrift auf S. 16926 beschreiben. Ein Schlüsselschritt dieser Elektrosynthese ist die anodische Oxidation eines Rhodacyclus zur Herbeiführung der reduktiven Eliminierung. Das Bild...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.