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Solid electrolyte with stable and fast Na+ ionic conductivity is of central importance in the development of all-solid-state sodium batteries. Here we present a novel Na+ conductor based on complex hydrides with composition of Na3NH2B12H12. It exhibits remarkable thermal stability up to 593 K and excellent electrochemical stable window up to 10 V (vs. Na+/Na). It demonstrates a high Na+ conductivity...
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