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The kinetic parameters for the “inversion substitution” reactions of Br-containing fire suppressants CH 3 Br and CF 3 Br with molecular oxygen CX 3 Br+O 2 →CX 3 O 2 +Br (X=H, F) have been obtained on the basis of computational study carried out by quantum chemistry methods and transition state theory (TST). The DFT/B3LYP approach has been used to obtain...
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