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Klick! Bei formalen [3+2]‐Cycloadditionen von 2‐Nitrosopyridin mit Allylstannanen bilden sich 4‐stannylsubstituierte Isoxazolidine. [Cu(MeCN)4]PF6 in Kombination mit einem Walphos‐Liganden ergibt exzellente Enantioselektivitäten bei hohen Ausbeuten. cis‐2‐Alkenylstannane als Nukleophile führen zu 3‐Alkyl‐4‐stannylsubstituierten Isoxazolidinen mit exzellenten Enantio‐ und Diastereoselektivitäten.
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