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Selektiver CO2‐Einfang in Gegenwart von N2 und H2O ist eine Sache für hydrophobe zeolithische Imidazolatgerüste (ZIFs) mit Chabazit‐Topologie. O. M. Yaghi und Mitarbeiter berichten in ihrer Zuschrift auf S. 10821 ff. über die Herstellung solcher Materialien, die drei Zyklen ohne Leistungsrückgang vollführen können. Zwischen den Zyklen waren die ZIFs jeweils mithilfe eines N2‐Stroms bei Raumtemperatur...
Hydrophobic zeolitic imidazolate frameworks (ZIFs) with the chabazite (CHA) topology are synthesized by incorporating two distinct imidazolate links. Zn(2‐mIm)0.86(bbIm)1.14 (ZIF‐300), Zn(2‐mIm)0.94(cbIm)1.06 (ZIF‐301), and Zn(2‐mIm)0.67(mbIm)1.33 (ZIF‐302), where 2‐mIm=2‐methylimidazolate, bbIm=5(6)‐bromobenzimidazolate, cbIm=5(6)‐chlorobenzimidazolate, and mbIm=5(6)‐methylbenzimidazolate, were prepared...
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