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Monodisperse Edelmetallnanopartikel (im Beispiel PdNPs) können in Gegenwart eines thiolfreien Tripeptids in wässriger Lösung gebildet werden, wie H. Wennemers et al. in der Zuschrift auf S. 8684 ff. beschreiben. Das Titelbild illustriert, wie das Peptid durch Komplexbildung mit Pd2+‐Ionen und deren Reduktion zu Pd0 die Nanopartikelbildung über das Ausbilden eines kompakten Peptidfilms um den Metallkern...
A combinatorial screening revealed the peptide H‐His‐d‐Leu‐d‐Asp‐NH2 (1) as an additive for the generation of monodisperse, water‐soluble palladium nanoparticles with average diameters of 3 nm and stabilities of over 9 months. The tripeptide proved to be also applicable for the size‐controlled formation of other noble‐metal nanoparticles (Pt and Au). Studies with close analogues of peptide 1 revealed...
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