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The photochemical reaction of C 60 with 3-trifluoromethyl-3-phenyldiazirine affords a photo-labeled C 60 derivative. The derivative was characterized by mass, UV–vis absorption, NMR spectroscopy, and X-ray crystallographic analysis. The redox potentials of this derivative were also investigated by means of CV and DPV. This photo-labeling method to the fullerene surface is expected...
By employing C 60 as a chemical probe, the photolysis of benzylchlorodiazirine has been proposed to form carbene and the rearranged products via the excited state.
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