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This review gives an insight into the growing field of transition metal-catalyzed cascades. More particularly, we have focused on the construction of complex molecules from acyclic precursors. Several approaches have been devised. We have not covered palladium-mediated cyclizations, multiple Heck reactions, or ruthenium-catalyzed metathesis reactions because they are discussed in others chapters of...
Radical tandem reactions—and in a wider context radical dominos or cascades—have attracted a lot of attention because of their intrinsic elegance and the construction of a broad and sometimes unique array of molecular architectures they allow in a single step. This review focuses on the latest progress in the design and development of new tandem reactions. The first part is devoted to intramolecular...
This review provides an insight into the activation of allenes by gold complexes toward nucleophilic attack. The various possible geometries of allene–gold species, from η2-allenes to η1 allylic cations, are described. From the data collected in the literature, it is clear that all of these intermediates have been met during computational analysis of reaction mechanisms. While some retain the stereochemical...
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