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Doublet emission from open‐shell molecules has demonstrated its research and application value in recent years. However, understandings of the photoluminescence mechanism of open‐shell molecules are far less than that of closed‐shell molecules, leading to challenges in molecular design of efficient doublet emission systems. Here we report a cerium(III) 4‐(9H‐carbozol‐9‐yl)phenyl‐tris(pyrazolyl)borate...
Photocatalytic hydrogen (H2) evolution represents a promising and sustainable technology. Covalent organic frameworks (COFs)‐based photocatalysts have received growing attention. A 2D fully conjugated ethylene‐linked COF (BTT‐BPy‐COF) was fabricated with a dedicated designed active site. The introduced bipyridine sites enable a facile post‐protonation strategy to fine‐tune the actives sites, which...
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