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The phase diagrams and thermodynamic basis for the Bi–Se and Zn–Se binary systems are analyzed in this work, where the CALPHAD technique is adopted and the associated solution model is applied for the liquid phase. Two binary associates, Bi2Se3 and ZnSe, are assumed to be present in Bi–Se and Zn–Se melts respectively. Bi3Se2, Bi2Se3 and ZnSe are treated as stoichiometric phases, while BiSe is described...
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