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A reaction sequence of regioselective peripheral bromination, Suzuki–Miyaura coupling with 2‐borylated thiophene or pyrrole, and oxidative ring‐closure with FeCl3 allowed the synthesis of heterole‐fused earring porphyrins 4Pd and 9Pd from the parent earring porphyrin 1. Differently pyrrole‐fused porphyrins 5H and 6H and their PdII complexes 5Pd and 6Pd were also synthesized. The structures of 4Pd,...
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