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Synthesis of functional 3D COFs with irreversible bond is challenging. Herein, 3D imide‐bonded COFs were constructed via the imidization reaction between phthalocyanine‐based tetraanhydride and 1,3,5,7‐tetra(4‐aminophenyl)adamantine. These two 3D COFs are made up of interpenetrated pts networks according to powder X‐ray diffraction and gas adsorption analyses. CoPc‐PI‐COF‐3 doped with carbon black...
Synthesis of functional 3D COFs with irreversible bond is challenging. Herein, 3D imide‐bonded COFs were constructed via the imidization reaction between phthalocyanine‐based tetraanhydride and 1,3,5,7‐tetra(4‐aminophenyl)adamantine. These two 3D COFs are made up of interpenetrated pts networks according to powder X‐ray diffraction and gas adsorption analyses. CoPc‐PI‐COF‐3 doped with carbon black...
Direct photoconversion of low‐concentration CO2 into a widely tunable syngas (i.e., CO/H2 mixture) provides a feasible outlet for the high value‐added utilization of anthropogenic CO2. However, in the low‐concentration CO2 photoreduction system, it remains a huge challenge to screen appropriate catalysts for efficient CO and H2 production, respectively, and provide a facile parameter to tune the CO/H...
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