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Design, Synthese und Anwendung von Benzolbioisosteren haben in den letzten 20 Jahren viel Aufmerksamkeit erfahren. In jüngster Zeit haben sich Bicyclo[2.1.1]hexane als äußerst attraktive Bioisostere für ortho‐ und meta‐substituierte Benzole erwiesen. In diesem Artikel beschreiben wir eine milde, skalierbare und übergangsmetallfreie Methode zur Herstellung von hochsubstituierten Bicyclo[2.1.1]hexanen...