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Photochemical oxidation of thiophene in n-octane/acetonitrile extraction system using O2 as oxidant was studied. Results obtained here can be used as the reference for the oxidative desulfurization of gasoline because thiophene is one of the main components containing sulfur in fluid catalytic cracking gasoline. A 500 w high-pressure mercury lamp was used as light source for irradiation and air was...
Photocatalytic oxidative kinetics of thiophene in n-octane/water extraction system was studied with nano-TiO2 powders as photocatalyst and O2 in air as oxidant. Influence of initial concentration of thiophene and addition of TiO2 on reaction rate constant and half time were investigated. Kinetics equation was founded. The results showed that the approviate addition of TiO2 was 0.1 g in 100 mL reaction...
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