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Effective passivation and stabilization of both the inside and interface of a perovskite layer are crucial for perovskite solar cells (PSCs), in terms of efficiency, reproducibility, and stability. Here, the first formamidinium lead iodide (δ‐FAPbI3) polymorph passivated and stabilized MAPbI3 PSCs are reported. This novel MAPbI3/δ‐FAPbI3 structure is realized via treating a mixed organic cation MA...
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