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Die räumliche Anordnung interstitieller Oxidladungsträger im Melilith La1.64Ca0.36Ga3O7.32 verringert die Ionenleitfähigkeit. Das komplexe Ordnungsmuster resultiert aus der Anpassung an die lokale Relaxation der Struktur um die interstitiellen Oxide, die über die einfache Bildung trigonaler GaO5‐Bipyramiden aus GaO4‐Tetraedern (siehe Bild; braun/orange/türkis: Ga, andere Farben: O) in fehlgeordneten...
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