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The CO2 absorption performance of aqueous 1-(2-hydroxyethyl)pyrrolidine (1-(2-HE)PRLD) was studied with respect to kinetics (i.e., in terms of the pseudo-first-order rate constant (ko) and second-order reaction rate constant (k2), obtained using the stopped-flow apparatus). CO2 equilibrium solubility and heat of CO2 absorption were evaluated at the temperature range of 293–313K in the 1-(2-HE)PRLD...
This work examined the relationship between the structure of various commercial tertiary amines and their activity in CO2 absorption/desorption in terms of rate of CO2 absorption, equilibrium CO2 loading, pKa and heat of CO2 absorption in order to establish possible guidelines for selection of tertiary amine components for amine blends. Results show that any electron donating group linked directly...
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