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Ein neuartiges Triphosphaazatriangulen, ein hydrophobes Gerüst mit ausgedehntem π‐System umgeben von hydrophilen Phosphinat‐Gruppen, wird von T. Hatakeyama et al. in ihrer Zuschrift auf S. 1451 vorgestellt. Die amphiphile Verbindung ermöglicht eine Lösungsmitteldampf‐induzierte reversible Einkristall‐zu‐Einkristall‐Umwandlung zwischen einem 3D‐MOF mit reversibler MeOH‐Sorption und einem 1D‐kolumnaren...
A triphosphaazatriangulene (H3L) was synthesized through an intramolecular triple phospha‐Friedel–Crafts reaction. The H3L triangulene contains three phosphinate groups and an extended π‐conjugated framework, which enables the stimuli‐responsive reversible transformation of [Cu(HL)(DMSO)⋅(MeOH)]n, a 3D‐MOF that exhibits reversible sorption characteristics, into (H3L⋅0.5 [Cu2(OH)4⋅6 H2O] ⋅4 H2O), a...
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