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Dissociative photoionization (DPI) of N2O at ∼20eV has been reinvestigated with threshold photoelectron–photoion coincidence (TPEPICO) velocity imaging. In threshold photoelectron spectrum, a shoulder peak at 20.045eV is observed close to the ground vibrational level of C2Σ+ state at 20.100eV. Through comparing the coincident mass spectra recorded at 20.045 and 20.100eV, the assignment of the shoulder...
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