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High efficiency and mechanical robustness are both crucial for the practical applications of all‐polymer solar cells (all‐PSCs) in stretchable and wearable electronics. In this regard, a series of new polymer acceptors (PAs) is reported by incorporating a flexible conjugation‐break spacer (FCBS) to achieve highly efficient and mechanically robust all‐PSCs. Incorporation of FCBS affords the effective...
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