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A novel europium complex [Eu2(C9N2O4H11)3(OH)2]Br ⋅ H2O derived from 1,3‐bis (1‐carboxylatoethyl)imidazolium bromide ([H2bcei]Br, C9N2O4H11=bcei2−) was synthesized by solvothermal method. [Eu2(C9N2O4H11)3(OH)2]Br ⋅ H2O possesses 3D structure constructed by Eu−O coordination bonds. In this complex, there are two coordinated environments around Eu3+, and Eu1 and Eu2 are eight‐ and seven‐ coordinated...
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