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The precise alignment of multiple layers of metal–organic framework (MOF) thin films, or MOF‐on‐MOF films, over macroscopic length scales is presented. The MOF‐on‐MOF films are fabricated by epitaxially matching the interface. The first MOF layer (Cu2(BPDC)2, BPDC=biphenyl‐4,4′‐dicarboxylate) is grown on an oriented Cu(OH)2 film by a “one‐pot” approach. Aligned second (Cu2(BDC)2, BDC=benzene 1,4‐dicarboxylate,...
Orientierte und funktionale MOF‐auf‐MOF‐Filme wurden durch epitaktisches Wachstum in Lösung hergestellt. In ihrer Zuschrift auf S. 6960 ff. zeigen M. Takahashi, C. J. Doonan et al., wie die Ausrichtung von mehrlagigen MOF‐Filmen auf einem orientierten Cu(OH)2‐Film genutzt werden kann, um diese Strukturen zu synthetisieren. Ag‐Nanopartikel in den ausgerichteten Poren selektiver Lagen der Filme zeigen...
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