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We report the characterization of the compound [K([2.2.2]crypt)]4[In8Sb13], which proves to contain a 1:1 mixture of [Sb@In8Sb12]3− and [Sb@In8Sb12]5−. The tri‐anion displays perfect Th symmetry, the first completely inorganic molecule to do so, and contains eight equivalent In3+ centers in a cube. The gas‐phase potential energy surface of the penta‐anion has eight equivalent minima where the extra...
Das erste gemischte In/Sb‐Zintl‐Anion, ein Cluster, der effektiv als [Sb@In8Sb12]4− auftritt, aber in Wahrheit eine 1:1‐Mischung aus [Sb@In8Sb12]3− und [Sb@In8Sb12]5− darstellt, wurde synthetisiert und strukturell charakterisiert, wie Z. M. Sun et al. in ihrer Zuschrift auf S. 8455 ff. berichten. Das Trianion zeigt perfekte Th‐Symmetrie und enthält acht äquivalente In3+‐Zentren auf den Ecken eines...
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