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In article number 1804770, Chunying Duan and co‐workers comprehensively survey recent asymmetric catalysis processes of metal–organic cages (MOCs) and metal–organic frameworks (MOFs) with chiral confined space that is analogous to the binding pocket of enzymes. The spatial constraints and shielding effects exhibit an ideal working yard to accelerate a series of novel asymmetric transformations with...
The effective synthesis of chiral compounds in a highly enantioselective manner is obviously attractive. Inspired by the enzymatic reactions that occur in pocket‐like cavities with high efficiency and specificity, chemists are seeking to construct catalysts that mimic this key feature of enzymes. Recent progress in supramolecular coordination chemistry has shown that metal–organic cages (MOCs) and...
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