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Interfacial charge separation and transfer are the main challenges of efficient semiconductor‐based Z‐scheme photocatalytic systems. Here, it is discovered that a Schottky junction at the interface between the BiVO4 {010} facet and Au is an efficient electron‐transfer route useful for constructing a high‐performance BiVO4{010}–Au–Cu2O Z‐scheme photocatalyst. Spectroscopic and computational studies...
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