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The isothermal crystallization of isomorphic Poly(hexamethylene adipate-co-butylene adipate) [P(HA-co-BA)], with the HA unit content ranged from 100 to 45 mol%, forming the Poly(hexamethylene adipate) [PHA] type crystal was investigated with DSC, FTIR and WAXD. The BA units were found adopting their all-trans conformation in the crystalline phase of PHA type crystal. The inclusion of the BA units...
It has been investigated the effects of poly(butylene succinate) (PBS) component on the fractionated crystallization, crystalline structure, and spherulite morphology of polymorphic poly(butylene adipate) (PBA) with melting temperature lower than that of PBS in their miscible binary blends. Fractionated crystallization of the PBA component occurs upon blending with PBS depending on the content and...
The crystallization behavior has been investigated for poly(hexamethylene sebacate-co-hexamethylene suberate)s [P(HSe-co-HSu)] and poly(hexamethylene suberate-co-hexamethylene adipate)s [P(HSu-co-HA)] copolyesters by differential scanning calorimeter (DSC), wide angle X-ray diffraction (WAXD) and Fourier transform infrared (FTIR) spectrometer. Cocrystallization of comonomer units was found in the...
By focusing on a range of fractions of medium-chain-length polyhydroxyalkanoates (mcl-PHA), a more in-depth understanding of the thermal properties and the crystalline structure has been gained. Dual-mode melting was observed for all the fractionated samples. Further DSC analysis revealed that such phenomenon was due to the presence of two crystalline phases (phase I and phase II), forming at different...
The outer surface of multi-walled carbon nanotubes (MWCNTs) was successfully modified with 7-bromo-9,9-dioctylfluorene-2-carbaldehyde by using 1,3-dipolar cycloaddition of azomethine reaction to introduce bromo functional groups. The peripheral bromo functional groups can be used to further react with AB-type monomers through Suzuki polycondensation to afford the PF-functionalized MWCNTs, which are...
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