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A study of the organic semiconductor F8TBT is presented, directly comparing a conventional form (F8TBT‐out) with a form with varied alkyl side‐chain position (F8TBT‐in), in terms of optical properties and device performance in light‐emitting‐diodes (LEDs). Computational simulations of the side‐chain position with respect to the TBT unit reveal geometrical differences between F8TBT‐out and F8TBT‐in...
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