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Herein, bioinspired total syntheses of A201A, A201D, and A201E based on a previously reported biosynthetic pathway are presented. The challenging 1,2‐cis‐furanoside, a core structure of the A201 family, was obtained by remote 2‐quinolinecarbonyl‐assisted glycosylation. We accomplished the total synthesis of A201A and A201E based on the critical 1,2‐cis‐furanoside moiety through late‐stage glycosylation...
Herein, bioinspired total syntheses of A201A, A201D, and A201E based on a previously reported biosynthetic pathway are presented. The challenging 1,2‐cis‐furanoside, a core structure of the A201 family, was obtained by remote 2‐quinolinecarbonyl‐assisted glycosylation. We accomplished the total synthesis of A201A and A201E based on the critical 1,2‐cis‐furanoside moiety through late‐stage glycosylation...
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