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Excitonic confinement greatly determines the charge carrier transport of photocatalysts. A molten salt modulation of excitonic confinement is herein demonstrated as formation of ultrafine carbon‐doped anatase TiO2 with grafted graphitic carbon nitride, which is rationalized as an excellent catalyst for overall CO2 photoreduction. Compared with bulk TiO2, the carbon‐doped TiO2 (M‐TiO2) possesses a...
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