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Compounds containing the [Mo6I8L6]2– ion in which L is an inorganic or organic ligand show remarkable photophysical properties. Similar properties were observed for the corresponding compounds based on octahedral tungsten clusters. The properties of these photosensitizers are significantly impacted by the six outer iodide ligands of [W6I8I6]2–. To analyze the role of the outer ligands, we prepared...
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