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Two commercially available TiO 2 catalysts were compared in the selective photocatalytic oxidation of cyclohexane: Hombikat UV100 (as received (H), and after calcination at 600°C (H600)), and Solaronix, S450. Hombikat UV100 shows the highest initial activity on a g −1 catalyst basis, followed by H600 and S450 with very similar activity profiles. All catalysts suffer from deactivation...
Anatase-structured Ti 1−x Zr x O 2 materials with x=0.00, 0.01 and 0.06, were prepared by a reverse microemulsion method, characterized, and tested as catalysts for the selective photo-oxidation of cyclohexane to cyclohexanone. In situ ATR-FTIR spectroscopy was used to evaluate the reaction. Zr incorporation into the anatase lattice enhances the surface acidity of TiO 2...
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