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A simple procedure is employed for the growth of silver nanoparticles (Ag NPs) onto the silicon substrate modified by poly(acrylic acid) (PAA) brushes, via: (1) surface-initiated ATRP of tert-butyl acrylate on Si surface to the preparation of poly(tert-butyl acrylate) brushes, (2) acid hydrolysis of PBA to the formation of PAA, and (3) in situ synthesis of Ag NPs via chemical reduction of AgNO3 in...
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