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Glassy LiPO3/crystalline Al2O3 and glassy LiPO3/crystalline ZrO2 (0–12.5 vol.% of oxide fillers) composite solid electrolytes have been prepared by glass matrix softening. Their thermal and transport properties have been investigated by differential scanning calorimetry (DSC) and impedance spectroscopy methods. The addition of ZrO2 leads to a decrease in the crystallization temperature of LiPO3 glass...
The dependence of the structure and properties of two series of glasses (100–x)LiPO3−xSiO2, x = 0–20 (series I) and 50Li2O−(50–x)P2O5−xSiO2, x = 0–10 (series II) were studied. The amorphous state of the composites was confirmed by XRD. In series II, a mixed glass-forming effect was revealed with a nonmonotonic increase of the glass transition temperature and electric conductivity. The structural features...
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