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We present in situ (x-ray diffraction) and ex situ (quenching) structural studies of crystalline, liquid, and glassy B2O3 up to 9 GPa and 1700 K, drawing equilibrium and nonequilibrium phase diagrams of B2O3. Particularly, we have determined the melting curve, the stability regions for crystalline B2O3 I and B2O3 II modifications, the regions of transformations, such as densification or crystallization,...
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